A mineral is a naturally occurring solid Solid is one of the major states of matter. It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a gas does. The atoms in a solid are tightly bound to each other, chemical substance In chemistry, a chemical substance is a material with a specific chemical composition that is formed through geological Geology is the science and study of the physical matter and energy that constitute the Earth. The field of geology encompasses the study of the composition, structure, properties, and history of the planet's physical material, the processes by which it is formed, moved, and changed, the history of life on Earth, and human interactions with the processes and that has a characteristic chemical composition In chemistry, the empirical formula of a chemical compound is the simplest whole number ratio of atoms of each element present in a compound. An empirical formula makes no reference to isomerism, structure, or absolute number of atoms. The empirical formula is used as standard for most ionic compounds, such as CaCl2, and for macromolecules, such, a highly ordered atomic structure The atom is a basic unit of matter consisting of a dense, central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons . The electrons of an atom are bound to the nucleus by the electromagnetic force. Likewise, a group of atoms can remain, and specific physical properties A physical property is any measurable property the value of which describes a physical system's state at any given moment in time. For that reason the changes in the physical properties of a system can be used to describe its transformations. By comparison, a rock In geology, rock is a naturally occurring solid aggregate of minerals and/or mineraloids is an aggregate of minerals and/or mineraloids A mineraloid is a mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amorphous glass and not a crystal. Jet is derived from decaying wood under extreme pressure. Opal is another mineraloid because and does not have a specific chemical composition. Minerals range in composition from pure elements A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. The term is also used to refer to a pure chemical substance composed of atoms with the same number of protons. Common examples of elements are iron, copper, silver, gold, hydrogen, carbon, and simple salts In chemistry, salts are ionic compounds that can result from the neutralization reaction of an acid and a base. Salts are ionic compounds composed of cations and anions (negative ions) so that the product is electrically neutral (without a net charge). These component ions can be inorganic such as chloride (Cl−), as well as organic such as to very complex silicates A silicate is a compound containing a silicon bearing anion. The great majority of silicates are oxides, but hexafluorosilicate and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as most planets and moons. Sand, Portland cement, and thousands of minerals with thousands of known forms.[1] The study of minerals is called mineralogy Mineralogy is the study of chemistry, crystal structure, and physical properties of minerals. Specific studies within mineralogy include the processes of mineral origin and formation, classification of minerals, their geographical distribution, as well as their utilization.

Contents

Mineral definition and classification

To be classified as a true mineral, a substance must be a solid Solid is one of the major states of matter. It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a gas does. The atoms in a solid are tightly bound to each other, and have a crystalline A crystal or crystalline solid is a solid material, whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is crystallography. The process of crystal formation via mechanisms of crystal growth is called structure. It must also be a naturally occurring, homogeneous substance with a defined chemical composition. Traditional definitions excluded organically derived material. However, the International Mineralogical Association The International Mineralogical Association is an international group of 38 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 4000 plus known mineral species. The IMA is affiliated with the International Union of Geological Sciences (IUGS) in 1995 adopted a new definition:

a mineral is an element or chemical compound that is normally crystalline and that has been formed as a result of geological processes.[2]

The modern classifications include an organic class – in both the new Dana and the Strunz classification Strunz classification is a scheme for categorizing minerals based upon their chemical composition, introduced by German mineralogist Karl Hugo Strunz in his 1941 Mineralogische Tabellen schemes.[3][4]

The chemical In chemistry, a chemical substance is a material with a specific chemical composition composition may vary between end members An endmember in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity. Minerals often can be described as solid solutions with varying compositions of some chemical elements, rather than as substances with an exact chemical formula. There may be two or more endmembers in a group or series of minerals of a mineral system. For example the plagioclase Plagioclase is an important series of tectosilicate minerals within the feldspar family. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a solid solution series, more properly known as the plagioclase feldspar series . This was first shown by the German mineralogist Johann Friedrich Christian feldspars Feldspars crystallize from magma in both intrusive and extrusive igneous rocks, as veins, and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rock comprise a continuous series from sodium Sodium is a metallic element with a symbol Na (from Latin natrium or Arabic ناترون natrun; perhaps ultimately from Egyptian netjerj) and atomic number 11. It is a soft, silvery-white, highly reactive metal and is a member of the alkali metals within "group 1" (formerly known as ‘group IA’). It has only one stable isotope, 23Na and silicon-rich albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. As such it represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula Na (NaAlSi3O8) to calcium Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth most abundant element by mass in the Earth's crust. Calcium is also the fifth most abundant dissolved ion in seawater by both molarity and mass, after sodium, chloride, and aluminium-rich anorthite Anorthite is the calcium endmember of plagioclase feldspar. Plagioclase is an abundant mineral in the Earth's crust. The formula of pure anorthite is Ca (CaAl2Si2O8) with four recognized intermediate compositions between. Mineral-like substances that don't strictly meet the definition are sometimes classified as mineraloids A mineraloid is a mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amorphous glass and not a crystal. Jet is derived from decaying wood under extreme pressure. Opal is another mineraloid because. Other natural-occurring substances are nonminerals A nonmineral is a substance found in a natural environment that does not satisfy the definition of a mineral and is not even a mineraloid. Many non-minerals are mined and have industrial or other uses similar to minerals, such as jewelry. Industrial minerals Industrial minerals are geological materials which are mined for their commercial value, which are not fuel and are not sources of metals (metallic minerals). They are used in their natural state or after beneficiation either as raw materials or as additives in a wide range of applications is a market term and refers to commercially valuable mined materials (see also Minerals and Rocks section below).

A crystal structure In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry. Patterns are located upon the points of a lattice, which is an array is the orderly geometric spatial arrangement of atoms The atom is a basic unit of matter that consists of a dense, central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons . The electrons of an atom are bound to the nucleus by the electromagnetic force. Likewise, a group of atoms can remain in the internal structure of a mineral. There are 14 basic crystal lattice In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry. Patterns are located upon the points of a lattice, which is an array arrangements of atoms in three dimensions, and these are referred to as the 14 "Bravais lattices Two Bravais lattices are often considered to be equivalent if they have isomorphic symmetry groups. In this sense, there are 14 possible Bravais lattices in three-dimensional space. The 14 possible symmetry groups of Bravais lattices are 14 of the 230 space groups". Each of these lattices can be classified into one of the seven crystal A crystal or crystalline solid is a solid material, whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is crystallography. The process of crystal formation via mechanisms of crystal growth is called systems, and all crystal structures currently recognized fit in one Bravais lattice and one crystal system. This crystal structure is based on regular internal atomic or ionic An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge. An anion , from the Greek word ἀνω (anο), meaning "up", is an ion with more electrons than protons, giving it a net negative charge (since electrons are negatively arrangement that is often expressed in the geometric form that the crystal takes. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by X-ray X-radiation is a form of electromagnetic radiation. X-rays have a wavelength in the range of 0.01 to 10 nanometers, corresponding to frequencies in the range 30 petahertz to 30 exahertz (3 × 1016 Hz to 3 × 1019 Hz) and energies in the range 120 eV to 120 keV. They are shorter in wavelength than UV rays and longer than gamma rays. In many diffraction. Chemistry and crystal structure together define a mineral. In fact, two or more minerals may have the same chemical composition, but differ in crystal structure (these are known as polymorphs). For example, pyrite The mineral pyrite, or iron pyrite, is an iron sulfide with the formula Fe and marcasite The mineral marcasite, sometimes called white iron pyrite, is iron sulfide . Marcasite is often mistakenly confused with pyrite, but marcasite is lighter and more brittle. Specimens of marcasite often crumble and break up due to the unstable crystal structure, and it is this crystal structure that is the main difference between marcasite and are both iron sulfide, but their arrangement of atoms differs. Similarly, some minerals have different chemical compositions, but the same crystal structure: for example, halite Halite occurs in vast beds of sedimentary evaporite minerals that result from the drying up of enclosed lakes, playas, and seas. Salt beds may be up to hundreds of meters thick and underlie broad areas. In the United States and Canada extensive underground beds extend from the Appalachian basin of western New York through parts of Ontario and (made from sodium and chlorine Chlorine (pronounced /ˈklɔəriːn/ KLOR-een, from the Greek word 'χλωρóς' , is the chemical element with atomic number 17 and symbol Cl. It is a halogen, found in the periodic table in group 17 (formerly VII, VIIa, or VIIb). As the chloride ion, which is part of common salt and other compounds, it is abundant in nature and necessary to), galena Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral (made from lead Lead is a main-group element with symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed to air. Lead has a shiny chrome-silver luster when it is melted into a and sulfur Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant, multivalent non-metal. Sulfur, in its native form, is a bright yellow crystalline solid. In nature, it can be found as the pure element and as sulfide and sulfate minerals. It is an essential element for life and is found in) and periclase Periclase occurs naturally in contact metamorphic rocks and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide (Mg (made from magnesium Magnesium is a chemical element with the symbol Mg, atomic number 12 and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust, where it constitutes about 2% by mass, and ninth in the known Universe as a whole. This preponderance of magnesium is related to the fact that it is easily and oxygen Oxygen (pronounced /ˈɒksɨdʒɨn/, OK-si-jin, from the Greek roots ὀξύς (acid, literally "sharp", from the taste of acids) and -γενής (-genēs) (producer, literally begetter), is the element with atomic number 8 and represented by the symbol O. It is a member of the chalcogen group on the periodic table, and is a highly) all share the same cubic crystal structure.

Crystal structure greatly influences a mineral's physical properties. For example, though diamond In mineralogy, diamond is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions. Diamond is renowned as a material with superlative and graphite The mineral graphite is one of the allotropes of carbon. It was named by Abraham Gottlob Werner in 1789 from the Greek γράφειν : "to draw/write", for its use in pencils, where it is commonly called lead, as distinguished from the actual metallic element lead. Unlike diamond (another carbon allotrope), graphite is an electrical have the same composition (both are pure carbon Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds. There are three naturally occurring isotopes, with 12C and 13C being stable, while 14C is radioactive, decaying with a half-life of), graphite is very soft, while diamond is the hardest of all known minerals. This happens because the carbon atoms in graphite are arranged into sheets which can slide easily past each other, while the carbon atoms in diamond form a strong, interlocking three-dimensional network.

There are currently more than 4,000 known minerals, according to the International Mineralogical Association The International Mineralogical Association is an international group of 38 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 4000 plus known mineral species. The IMA is affiliated with the International Union of Geological Sciences (IUGS), which is responsible for the approval of and naming of new mineral species found in nature. Of these, perhaps 100 can be called "common", 50 are "occasional", and the rest are "rare" to "extremely rare".

Differences between minerals and rocks

A mineral is a naturally occurring solid with a definite chemical composition and a specific crystalline structure. A rock In geology, rock is a naturally occurring solid aggregate of minerals and/or mineraloids is an aggregate of one or more minerals. (A rock may also include organic remains and mineraloids A mineraloid is a mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amorphous glass and not a crystal. Jet is derived from decaying wood under extreme pressure. Opal is another mineraloid because.) Some rocks are predominantly composed of just one mineral. For example, limestone is a sedimentary rock composed almost entirely of the mineral calcite. Other rocks contain many minerals, and the specific minerals in a rock can vary widely. Some minerals, like quartz, mica or feldspar are common, while others have been found in only four or five locations worldwide. The vast majority of the rocks of the Earth's crust consist of quartz, feldspar, mica, chlorite, kaolin, calcite, epidote, olivine, augite, hornblende, magnetite, hematite, limonite and a few other minerals.[5] Over half of the mineral species known are so rare that they have only been found in a handful of samples, and many are known from only one or two small grains.

Commercially valuable minerals and rocks are referred to as industrial minerals. Rocks from which minerals are mined for economic purposes are referred to as ores (the rocks and minerals that remain, after the desired mineral has been separated from the ore, are referred to as tailings).

Mineral composition of rocks

A main determining factor in the formation of minerals in a rock mass is the chemical composition of the mass, for a certain mineral can be formed only when the necessary elements are present in the rock. Calcite is most common in limestones, as these consist essentially of calcium carbonate; quartz is common in sandstones and in certain igneous rocks which contain a high percentage of silica.

Other factors are of equal importance in determining the natural association or paragenesis of rock-forming minerals, principally the mode of origin of the rock and the stages through which it has passed in attaining its present condition. Two rock masses may have very much the same bulk composition and yet consist of entirely different assemblages of minerals. The tendency is always for those compounds to be formed which are stable under the conditions under which the rock mass originated. A granite arises by the consolidation of a molten magma at high temperatures and great pressures and its component minerals are those stable under such conditions. Exposed to moisture, carbonic acid and other subaerial agents at the ordinary temperatures of the Earth's surface, some of these original minerals, such as quartz and white mica are relatively stable and remain unaffected; others weather or decay and are replaced by new combinations. The feldspar passes into kaolinite, muscovite and quartz, and any mafic minerals such as pyroxenes, amphiboles or biotite have been present they are often altered to chlorite, epidote, rutile and other substances. These changes are accompanied by disintegration, and the rock falls into a loose, incoherent, earthy mass which may be regarded as a sand or soil. The materials thus formed may be washed away and deposited as sandstone or siltstone. The structure of the original rock is now replaced by a new one; the mineralogical constitution is profoundly altered; but the bulk chemical composition may not be very different. The sedimentary rock may again undergo metamorphism. If penetrated by igneous rocks it may be recrystallized or, if subjected to enormous pressures with heat and movement during mountain building, it may be converted into a gneiss not very different in mineralogical composition though radically different in structure to the granite which was its original state.[5]

Physical properties of minerals

Classifying minerals can range from simple to very difficult. A mineral can be identified by several physical properties, some of them being sufficient for full identification without equivocation. In other cases, minerals can only be classified by more complex chemical or X-ray diffraction analysis; these methods, however, can be costly and time-consuming.

Physical properties commonly used are:[1]

Talc Rough diamond.
  1. Talc Mg3Si4O10(OH)2
  2. Gypsum CaSO4·2H2O
  3. Calcite CaCO3
  4. Fluorite CaF2
  5. Apatite Ca5(PO4)3(OH,Cl,F)
  6. Orthoclase KAlSi3O8
  7. Quartz SiO2
  8. Topaz Al2SiO4(OH,F)2
  9. Corundum Al2O3
  10. Diamond C (pure carbon)

Chemical properties of minerals

Minerals may be classified according to chemical composition. They are here categorized by anion group. The list below is in approximate order of their abundance in the Earth's crust. The list follows the Dana classification system[1][7] which closely parallels the Strunz classification.

Silicate class

Quartz

The largest group of minerals by far are the silicates (most rocks are ≥95% silicates), which are composed largely of silicon and oxygen, with the addition of ions such as aluminium, magnesium, iron, and calcium. Some important rock-forming silicates include the feldspars, quartz, olivines, pyroxenes, amphiboles, garnets, and micas.

Carbonate class

The carbonate minerals consist of those minerals containing the anion (CO3)2− and include calcite and aragonite (both calcium carbonate), dolomite (magnesium/calcium carbonate) and siderite (iron carbonate). Carbonates are commonly deposited in marine settings when the shells of dead planktonic life settle and accumulate on the sea floor. Carbonates are also found in evaporitic settings (e.g. the Great Salt Lake, Utah) and also in karst regions, where the dissolution and reprecipitation of carbonates leads to the formation of caves, stalactites and stalagmites. The carbonate class also includes the nitrate and borate minerals.

Sulfate class

Sulfate minerals all contain the sulfate anion, SO42−. Sulfates commonly form in evaporitic settings where highly saline waters slowly evaporate, allowing the formation of both sulfates and halides at the water-sediment interface. Sulfates also occur in hydrothermal vein systems as gangue minerals along with sulfide ore minerals. Another occurrence is as secondary oxidation products of original sulfide minerals. Common sulfates include anhydrite (calcium sulfate), celestine (strontium sulfate), barite (barium sulfate), and gypsum (hydrated calcium sulfate). The sulfate class also includes the chromate, molybdate, selenate, sulfite, tellurate, and tungstate minerals.

Halide class

Halite

The halide minerals are the group of minerals forming the natural salts and include fluorite (calcium fluoride), halite (sodium chloride), sylvite (potassium chloride), and sal ammoniac (ammonium chloride). Halides, like sulfates, are commonly found in evaporite settings such as salt lakes and landlocked seas such as the Dead Sea and Great Salt Lake. The halide class includes the fluoride, chloride, bromide and iodide minerals.

Oxide class

Oxide minerals are extremely important in mining as they form many of the ores from which valuable metals can be extracted. They also carry the best record of changes in the Earth's magnetic field. They commonly occur as precipitates close to the Earth's surface, oxidation products of other minerals in the near surface weathering zone, and as accessory minerals in igneous rocks of the crust and mantle. Common oxides include hematite (iron oxide), magnetite (iron oxide), chromite (iron chromium oxide), spinel (magnesium aluminium oxide – a common component of the mantle), ilmenite (iron titanium oxide), rutile (titanium dioxide), and ice (hydrogen oxide). The oxide class includes the oxide and the hydroxide minerals.

Sulfide class

Many sulfide minerals are economically important as metal ores. Common sulfides include pyrite (iron sulfide – commonly known as fools' gold), chalcopyrite (copper iron sulfide), pentlandite (nickel iron sulfide), and galena (lead sulfide). The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, and the sulfosalts (sulfur and a second anion such as arsenic).

Phosphate class

The phosphate mineral group actually includes any mineral with a tetrahedral unit AO4 where A can be phosphorus, antimony, arsenic or vanadium. By far the most common phosphate is apatite which is an important biological mineral found in teeth and bones of many animals. The phosphate class includes the phosphate, arsenate, vanadate, and antimonate minerals.

Element class

The elemental group includes native metals and intermetallic elements (gold, silver, copper), semi-metals and non-metals (antimony, bismuth, graphite, sulfur). This group also includes natural alloys, such as electrum (a natural alloy of gold and silver), phosphides, silicides, nitrides and carbides (which are usually only found naturally in a few rare meteorites).

Organic class

The organic mineral class includes biogenic substances in which geological processes have been a part of the genesis or origin of the existing compound.[2] Minerals of the organic class include various oxalates, mellitates, citrates, cyanates, acetates, formates, hydrocarbons and other miscellaneous species.[3] Examples include whewellite, moolooite, mellite, fichtelite, carpathite, evenkite and abelsonite.

See also

Book:Mineralogy
Books are collections of articles that can be downloaded or ordered in print.

References

  1. ^ a b c Dana, James D. (March 6, 1985). Hurlbut, Cornelius S.; Klein, Cornelis. eds. Manual of Mineralogy (20 ed.). John Wiley & Sons Inc. ISBN 0-471-80580-7. free older version: 1912 edition
  2. ^ a b Nickel, Ernest H. (June 1995). "The definition of a mineral". The Canadian Mineralogist 33 (3): 689–690. http://www.canmin.org/cgi/content/abstract/33/3/689. alt version
  3. ^ a b Dana Classification 8th edition – Organic Compounds
  4. ^ Strunz Classification – Organic Compounds
  5. ^ a b This article incorporates text from the article "Petrology" in the Encyclopædia Britannica, Eleventh Edition, a publication now in the public domain.
  6. ^ USGS Photo glossary of volcano terms
  7. ^ Dana classification – Minerals.net

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